Polycyclic Arenes and Heteroarenes

Polycyclic Arenes and Heteroarenes

Edited by an innovator in the field, who has gathered an international team of well-established experts, this is a comprehensive overview of the rapidly developing field of polycyclic (hetero)arenes, specifically highlighting on their ...

Author: Qian Miao

Publisher: John Wiley & Sons

ISBN: 9783527338474

Category: Science

Page: 360

View: 888

Graphene, a giant molecule containing carbon atoms packed in a honeycomb lattice, is an extreme case of the compound class known as polycyclic arenes. Introduction of hetero-atoms, such as B and N, to the _-backbones of polycyclic arenes results in interesting heteroarene molecules that are structurally similar to their hydrocarbon analogues but which show different properties. Polycyclic arenes and heteroarenes play an important role in various fields such as organic electronics, medicine or energy. The editor, one of the leaders in the field, has gathered an international team of well-established experts, to provide this comprehensive overview of the rapidly developing field of polycyclic (hetero) arenes. Their molecular design and the latest synthetic procedures, as well as chemical and physical properties are specifically highlighted. Each chapter is dedicated to a specific compound class, the first eight covering polycyclic arenes, including both planar and non-planar conjugated molecules, while chapters nine to twelve deal with polycylic heteroarenes according to the heteroatoms, namely N, B, S and P. Important current and emergent applications in the field are also discussed, ranging from molecular sensors to electronic devices. The result is an essential reference for researchers in synthetic and physical organic chemistry, supra-molecular chemistry, and materials science.
Categories: Science

Biophysical Aspects

Biophysical Aspects

Ionization Potentials of Molecules : Radical Cation Formation A very large
number of ionization potentials of 7 HOMOs in substituted benzenes , ethylenes ,
polycyclic arenes , and heteroarenes has accumulated in the literature . We have
 ...

Author: Joel F. Liebman

Publisher: Wiley-VCH Verlag GmbH

ISBN: 0895733366

Category: Biochemistry

Page: 405

View: 209

Categories: Biochemistry

Advances in Mass Spectrometry

Advances in Mass Spectrometry

METHYL DERIVATIVES OF POLYCYCLIC ARENES AND OF HETEROARENES
Two additional effects regarding intensity and stabilization of benzyl analogous
cations can be expected when toluene is inserted into polycyclic arenes .

Author:

Publisher:

ISBN: UVA:X001383901

Category: Hydrocarbons

Page:

View: 169

Categories: Hydrocarbons

Chemtracts

Chemtracts

Borylation of heteroarenes can be low yielding in cases where coordination to
iridium appears to prevent formation of ... dtbbpy catalyst has also been used for
borylation of polycyclic arenes , including napthalenes , pyrenes , and perylenes .

Author:

Publisher:

ISBN: UOM:39015072610408

Category: Biochemistry

Page:

View: 365

Categories: Biochemistry

Chemische Berichte Recueil

Chemische Berichte Recueil

... is further extented by combining phosphorus centers and nitrogen or oxygen
donor atoms in P / N ligands ( 3 ) and P / O ligands ( 4 ) . In the context of our
concept of using polycyclic arenes and heteroarenes as rigid carbon skeletons
for the ...

Author:

Publisher:

ISBN: CHI:46830379

Category: Chemistry, Inorganic

Page:

View: 135

Categories: Chemistry, Inorganic

Directory of Graduate Research

Directory of Graduate Research

TEL : ( 805 ) 8932515 FAX : ( 805 ) 893-4120 E - Mail : kaskaa chem.ucsb.edu
M. W. Haenel , S. Oevers , S. Hillebrand and W. C. Kaska , Polycyclic arenes and
heteroarenes as backbones of diphosphine / amine ligands for thermostable ...

Author:

Publisher:

ISBN: UCSD:31822032480691

Category: Chemistry

Page:

View: 408

Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.
Categories: Chemistry

Reviews on Heteroatom Chemistry

Reviews on Heteroatom Chemistry

Other models , Alkyl substituted ethylens , arenes and heteroarenes , incidence
on chemical reactivity , creation of Gear Effect . ... 47 Tetsuo Otsubo and Kazuo
Takimiya Peri - Dichalcogen Bridged Polycyclic Aromatic Hydrocarbons as Novel
 ...

Author:

Publisher:

ISBN: CORNELL:31924080481801

Category: Chemistry, Physical and theoretical

Page:

View: 598

Categories: Chemistry, Physical and theoretical

Bulletin of the Chemical Society of Japan

Bulletin of the Chemical Society of Japan

... those used for typical arenes , heteroarenes are also borylated with B2pin2 or
HBpin ( Entries 7 – 13 ) . The protocol has been used successfully for borylation
of C - H bonds of azulene , 58 ferrocene and Cp - metal complexes , 59 polycyclic
 ...

Author: Nihon Kagakkai

Publisher:

ISBN: UOM:39015072634028

Category: Chemistry

Page:

View: 551

Categories: Chemistry

Handbook of C H Transformations

Handbook of C H Transformations

Even heteroarenes are more susceptible to dioxirane oxidation than C - H bonds
, whereas electron - rich and polycyclic arenes are only moderately tolerant , but
electron - poor arenes usually resist oxidation by dioxiranes . N - oxides and N ...

Author: Gerald Dyker

Publisher:

ISBN: UOM:39076002565765

Category: Organic compounds

Page: 661

View: 156

Categories: Organic compounds

Book of Abstracts

Book of Abstracts

... heteracyclo butanes hetero heteroarenes hexatriene Hexavalent hexayne
hexazinone hexene HF HI hfac hi hibiscus ... hetero duplex ANYL 0197
Thermostable homogeneous catalysts based on polycyclic arenes an INOR 1325
Synthesis ...

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Publisher:

ISBN: PSU:000043534425

Category: Chemistry

Page:

View: 987

Categories: Chemistry

Encyclopedia of Reagents for Organic Synthesis

Encyclopedia of Reagents for Organic Synthesis

In the case of acridine and phenanthridine the Na NH2 Ph ( 12 ) Et20,0 ° C
substitution product is an amino heteroarene . ... Treatment of unsaturated
hydrocarbons ( e.g. stilbene ) , unsaturated nitrogen compounds , or polycyclic
arenes with ...

Author: Leo A. Paquette

Publisher:

ISBN: PSU:000046360465

Category: Chemical tests and reagents

Page: 6223

View: 351

This reference contains an authoritative and systematic description of the use of all reagents in organic chemistry.
Categories: Chemical tests and reagents

Applied and Environmental Microbiology

Applied and Environmental Microbiology

Dioxygenase - catalysed formation of cis / trans dihydrodiol metabolites of mono-
and bi - cyclic heteroarenes . J. Chem . Soc . Chem . ... Oxidative metabolism of
polycyclic hydrocarbons by soil Pseudomonads . Nature ( London ) 182 ...

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Publisher:

ISBN: NWU:35558003746894

Category: Microbial ecology

Page:

View: 246

Categories: Microbial ecology

Physics Briefs

Physics Briefs

Author:

Publisher:

ISBN: STANFORD:36105001258875

Category: Physics

Page:

View: 581

Categories: Physics

Palladium Reagents and Catalysts

Palladium Reagents and Catalysts

The product 86 was transformed into a variety of polycyclic aromatic compounds
such as 87 and 88 [ 83 ] . The polycyclic heteroarene - annulated
cyclopentadiene 90 is prepared by the coupling of 3 - iodopyridine and
dicyclopentadiene ( 89 ) ...

Author: Jiro Tsuji

Publisher: John Wiley & Sons Incorporated

ISBN: UOM:39015055710860

Category: Science

Page: 560

View: 700

Basic chemistry of organopalladium compounds; Classification of the reactions involving Pd(II) compounds and Pd(O) complexes.
Categories: Science

Dissertation Abstracts International

Dissertation Abstracts International

... we were able to develop several novel solid phase syntheses of 2 - methyl
indolines , polycyclic indolines , 2 - methyl ... In Chapter 3 N - ( alkane - , arene -
and heteroarene - sulfonyl ) benzotriazoles were prepared in one - pot , in yields
of ...

Author:

Publisher:

ISBN: STANFORD:36105121649201

Category: Dissertations, Academic

Page:

View: 905

Categories: Dissertations, Academic

The Chemistry of Heterocycles

The Chemistry of Heterocycles

The book presents a practical guide to international nomenclature, including discussions of fused ring systems, heteroatoms with abnormal valences, and bridged, spiro and polycyclic heterocycles.

Author: Vishnu Ji Ram

Publisher: Elsevier

ISBN: 9780128192115

Category: Science

Page: 503

View: 181

The Chemistry of Heterocycles: Chemistry of Six to Eight Membered N,O, S, P and Se Heterocycles details the chemistry, behavior and potential of these important structures. The book presents a practical guide to international nomenclature, including discussions of fused ring systems, heteroatoms with abnormal valences, and bridged, spiro and polycyclic heterocycles. Three membered heterocycles are then the focus, along with their thermodynamic properties and importance in natural products, medicines, materials, and their unique aspects, such as strain, basicity and reactivity. Additional chapters cover 100 key heterocycle structures, from Azetidines, Pyrroles and Pyridines, to Benzoxepines and Oxocanes. Final chapters explore cutting-edge advances in the development of phosphorus and selenium based heterocycles. Provides clear, detailed information on each heterocyclic group, including structural features, such as ring strain, basicity, synthesis and reactivity towards electrophilic and nucleophilic reagents Highlights the latest advances in the field, including phosphorous and selenium-based heterocycles supported by numerous illustrations Includes details of functionalized heterocycles used as synthons for the construction of various arenes and heteroarenes
Categories: Science