Transition metals for organic synthesis

building blocks and fine chemicals

Author: Matthias Beller,Carsten Bolm

Publisher: Vch Verlagsgesellschaft Mbh

ISBN: 9783527306138

Category: Science

Page: 652

View: 935

Already in its second edition, here over 70 internationally renowned authors cover the vast range of possible applications for transition metals in industry as well as academia. This two-volume work presents the current state of research and applications in this economically and scientifically important area of organic synthesis as well as for the production of fine chemicals. Over 1,000 illustrations and the balanced presentation allow readers fast access to the thorough compilation of applications, making this an indispensable work for everyone working with such metals whether professionally or engaged in academic research.
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Organometallchemie

Author: Christoph Elschenbroich

Publisher: Springer-Verlag

ISBN: 3322993930

Category: Science

Page: 756

View: 8431

Ziel dieses Buches ist die Vermittlung gründlicher Kenntnisse der Organometallchemie der Haupt- und Nebengruppenelemente, etwa im zeitlichen Rahmen einer Vorlesung von vier Semesterwochenstunden. Hierbei kommen sowohl synthetische, strukturelle, spektroskopische, bindungstheoretische und mechanistische als auch anwendungsbezogene Aspekte zur Sprache. Gegenüber früheren Auflagen wurden neben zahlreichen Aktualisierungen vor allem die Organometallkatalyse und die Organometallchemie der f-Elemente verstärkt.
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Modern Rhodium-Catalyzed Organic Reactions

Author: P. Andrew Evans

Publisher: John Wiley & Sons

ISBN: 352760409X

Category: Science

Page: 496

View: 3353

Rhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for the dramatic increase in the number of articles that have recently emerged on the topic. P. Andrew Evans, the editor of this much-needed book, has assembled an internationally renowned team to present the first comprehensive coverage of this important area. The book features contributions from leaders in the field of rhodium-catalyzed reactions, and thereby provides a detailed account of the most current developments, including: Rhodium-Catalyzed Asymmetric Hydrogenation (Zhang) Rhodium-Catalyzed Hydroborations and Related Reactions (Brown) Rhodium-Catalyzed Asymmetric Addition of Organometallic Reagents to Electron Deficient Olefins (Hayashi) Recent Advances in Rhodium(I)-Catalyzed Asymmetric Olefin Isomerization and Hydroacylation Reactions (Fu) Stereoselective Rhodium(I)-Catalyzed Hydroformylation and Silylformylation Reactions and Their Application to Organic Synthesis (Leighton) Carbon-Carbon Bond-Forming Reactions Starting from Rh-H or Rh-Si Species (Matsuda) Rhodium(I)-Catalyzed Cycloisomerization and Cyclotrimerization Reactions (Ojima) The Rhodium(I)-Catalyzed Alder-ene Reaction (Brummond) Rhodium-Catalyzed Nucleophilic Ring Cleaving Reactions of Allylic Ethers and Amines (Fagnou) Rhodium(I)-Catalyzed Allylic Substitution Reactions and their Applications to Target Directed Synthesis (Evans) Rhodium(I)-Catalyzed [2+2+1] and [4+1] Carbocyclization Reactions (Jeong) Rhodium(I)-Catalyzed [4+2] and [4+2+2] Carbocyclizations (Robinson) Rhodium(I)-Catalyzed [5+2], [6+2], and [5+2+1] Cycloadditions: New Reactions for Organic Synthesis (Wender) Rhodium(II)-Stabilized Carbenoids Containing both Donor and Acceptor Substituents (Davies) Chiral Dirhodium(II)Carboxamidates for Asymmetric Cyclopropanation and Carbon-Hydrogen Insertion Reactions (Doyle) Cyclopentane Construction by Rhodium(II)-Mediated Intramolecular C-H Insertion (Taber) Rhodium(II)-Catalyzed Oxidative Amination (DuBois) Rearrangement Processes of Oxonium and Ammonium Ylides Formed by Rhodium(II)-Catalyzed Carbene-Transfer (West) Rhodium(II)-Catalyzed 1,3-Dipolar Cycloaddition Reactions (Austin) "Modern Rhodium-Catalyzed Organic Reactions" is an essential reference text for researchers at all levels in the general area of organic chemistry. This book provides an invaluable overview of the most significant developments in this important area of research, and will no doubt be an essential text for researchers at academic institutions and professionals at pharmaceutical/agrochemical companies.
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Hydrosilylation

A Comprehensive Review on Recent Advances

Author: Bogdan Marciniec

Publisher: Springer Science & Business Media

ISBN: 1402081723

Category: Science

Page: 408

View: 921

For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
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Iron Catalysis in Organic Chemistry

Reactions and Applications

Author: Bernd Plietker

Publisher: John Wiley & Sons

ISBN: 3527623280

Category: Science

Page: 295

View: 2789

This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.
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Organische Chemie

Studieren kompakt

Author: Paula Yurkanis Bruice

Publisher: Pearson Deutschland GmbH

ISBN: 3868941029

Category:

Page: 1165

View: 6157

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Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 47a

Alkenes

Author: Armin de Meijere

Publisher: Georg Thieme Verlag

ISBN: 313178461X

Category: Science

Page: 632

View: 465

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab.// The content of this e-book was originally published in November 2009.
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Comprehensive Organometallic Chemistry III

From Fundamentals to Applications

Author: D. M. P. Mingos,Gerard Parkin

Publisher: Pergamon

ISBN: 9780080445908

Category: Science

Page: 9000

View: 1579

Comprehensive Organometallic Chemistry, 3rd Edition (COMC-III), is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. * Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights. * Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus. * Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area.
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Copper-Catalyzed Asymmetric Synthesis

Author: Alexandre Alexakis,Norbert Krause,Simon Woodward

Publisher: John Wiley & Sons

ISBN: 3527664599

Category: Science

Page: 472

View: 493

This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications. This is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies.
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Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 40a

Amines and Ammonium Salts

Author: N.A

Publisher: Georg Thieme Verlag

ISBN: 3131783613

Category: Science

Page: 844

View: 9170

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab.// The content of this e-book was originally published in November 2008.
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Metal-catalysis in Industrial Organic Processes

Author: Royal Society of Chemistry (Great Britain)

Publisher: Royal Society of Chemistry

ISBN: 0854041508

Category: Education

Page: 290

View: 3836

Catalysis underpins most modern industrial organic processes. It has become an essential tool in creating a 'greener' chemical industry by replacing more traditional stoichiometric reactions, which have high energy consumption and high waste production, with mild processes which increasingly resemble Nature's enzymes. Metal-Catalysis in Industrial Organic Processes considers the major areas of the field and discusses the logic of using catalysis in industrial processes. This popular book, now available as softback, provides information on oxidation, hydrogenation, carbonylation, C-C bond formation, metathesis and polymerization processes, as well as on the mechanisms involved. In addition two appendices offer a concise treatment of homogeneous and heterogenous catalysis. Numerous exercises referring to problems of catalytic processes, and research perspectives complete the book. This definitive reference source, written by practising experts in the field, provides detailed and up-to-date information on key aspects of metal catalysis.
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Subject Guide to Books in Print

An Index to the Publishers' Trade List Annual

Author: N.A

Publisher: N.A

ISBN: N.A

Category: American literature

Page: N.A

View: 1866

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Late Transition Metal Polymerization Catalysis

Author: Bernhard Rieger

Publisher: Wiley-VCH Verlag GmbH

ISBN: 9783527304356

Category: Technology & Engineering

Page: 331

View: 2265

Even some fifty years after their discovery, transition metals have lost none of their fascination. The use of complex compounds in these elements has not only revolutionized synthesis in the laboratory, but has also led to them playing an important role in many industrial applications. Each year, millions of tons of plastics are produced around the world and, by varying the ligands in the catalytically active compounds, the properties of the resulting polymers can even be tailored for use. For this purpose, sandwich compounds from early transition metals have been common until now, but interest has focused increasingly on the late transition metals. In this book, the world's leading authors from research and industry discuss the latest developments in research into palladium, zinc, iron and nickel catalysis. In so doing, they systematically introduce readers to the basic principles and illustrate how these innovative catalysts can be effectively used for polymerizations. The result is an ideal reference work, invaluable for every organic chemist working in catalysis or polymer research.
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Science of Synthesis: Catalytic Oxidation in Organic Synthesis

Author: Kilian Muniz

Publisher: Georg Thieme Verlag

ISBN: 3132012610

Category: Science

Page: 880

View: 2171

The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. “Science of Synthesis: Catalytic Oxidation in Organic Synthesis” includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.
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Lewis Acids in Organic Synthesis

Author: Hisashi Yamamoto

Publisher: Wiley-VCH Verlag GmbH

ISBN: N.A

Category: Science

Page: 995

View: 6510

The use of Lewis acids in organic synthesis, especially in catalysis is one of the most rapidly developing fields in synthetic organic chemistry. In addition, Lewis acid catalysis is one of the key technologies for asymmetric synthesis, and combinatorial chemistry as well as for large-scale production. Until now, pertinent information on these topics was scattered throughout the literature. Although review articles have appeared,it was difficult for the researcher to compare different methods based on Lewis acids. This two-volume handbook, edited and written by an outstanding team of experts in the field, fills this gap! This book is based on a classification according to metal centre of these electron-deficient compounds, allowing an in-depth treatment of the characteristics, benefits and limitations of each class of acid. Extensive cross-referencing and a comprehensive index enables readers to quickly find the solution to their synthesis problem. The chemical community will welcome this as a source of inspiration and invaluable reference for daily work.
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Journal

Author: American Chemical Society

Publisher: N.A

ISBN: N.A

Category: Chemistry

Page: N.A

View: 6743

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