Polymer Syntheses

Author: Stanley R. Sandler,Wolf Karo

Publisher: Elsevier

ISBN: 0080925553

Category: Science

Page: 427

View: 1240

This revised and updated Second Edition of Polymer Synthesis II continues in the tradition of Volume I in presenting detailed laboratory instructions for the preparation of various polymers. Each chapter is organized by functional groups, and each chapter not only presents preparative methods, but also includes a brief introductory summary, reviews of the very latest journal articles and patents, and safety hazards and precautions. Procedures have been chosen on the basis of safety considerations and ease of being carried out with standard laboratory equipment. This comprehensive treatment of each polymer group makes Polymer Synthesis II an indispensable guide for industrial and academic chemists as well as for students in the field. Key Features * This revised edition: * Covers each polymer class, heavily referencing these with patent literature to illustrate commercial applications * Provides new and updated information for each functional group, including: * Curing agents for epoxy resins * Polymerization of vinyl ethers and copolymers * Polyvinyl silfides * Polymerization of vinyl pyrrolidone and copolymers * Features expanded data tables and updated references * Presents numerous citations to new catalysts for each polymer preparation involving ureas * Includes a new section--Complex Formulation--involving the preparation of polyacrylic acid and its copolymers * Contains many new preparations, including: * Preparation of t-butyl acrylate copolymers using the Teyssie Method * Template polymerization of vinylimidazole on polymethacrylic acid * Polymerization of aqueous acrylic acid using AIBN * Preparation of polyketals by transketalization * Copolymerization of maleic anhydride with ethyl vinyl ether * Complex and template polymerizations
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Polymer Syntheses

Author: Stanley Sandler

Publisher: Elsevier

ISBN: 0323145272

Category: Science

Page: 582

View: 4548

Polymer Syntheses, Volume I presents detailed laboratory instructions for the preparation of polymers by different functional group classes. This book provides the laboratory procedures for the preparation of polymers containing phosphorus in various oxidation states. Organized into 15 chapters, this volume begins with an overview of some selected preparative methods for carrying out the major methods of polymerization in the laboratory. This text then examines the synthesis of phosphonitrilic polymers. Other chapters consider the synthesis of peroxide and hydroperoxide free radical initiators. This book discusses as well the principles involved in the preparation of emulsion polymers, which are applicable to the preparation of polymers of a wide variety of vinyl monomers and many copolymerizations. The final chapter deals with the chemistry of organometallic and organometalloid peroxides. This book is a valuable resource for chemists involved in the designing of phosphorus polymers to meet fire retardant requirements of various products.
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Polymer Synthesis:

Author: Stanley R. Sandler,Wolf Karo

Publisher: Academic Press

ISBN: 9781493301881

Category: Science

Page: 512

View: 8076

This revised and updated second edition of Polymer Syntheses, Volume I brings together useful preparative methods for polymers and resins by functional group type that are of interest to both academic and industrial researchers. Several new directions for polymerization procedures have been included and are organized by various methodologies. Tables of physical property data and preparations make this book a valuable addition to any research library or research group. Key Features * Provides detailed directions for the synthesis of various functional groups * Includes up-to-date references to the journal literature and patents (foreign and domestic) * Reviews the chemistry for each functional group and suggests where additional research is needed
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Conjugated Polymer Synthesis

Methods and Reactions

Author: Yoshiki Chujo

Publisher: John Wiley & Sons

ISBN: 3527632689

Category: Technology & Engineering

Page: 318

View: 1392

Edited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds. As such, it describes every important compound class, including polysilanes, organoboron compounds, and ferrocene-containing conjugated polymers. An indispensable source for every synthetic polymer chemist.
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Polymer Syntheses

Author: Stanley R. Sandler,Wolf Karo

Publisher: N.A

ISBN: N.A

Category: Science

Page: 424

View: 8701

This volume, which completes the Second Edition of this widely respected three-volume set, continues the tradition of providing detailed and concise laboratory instructions for the preparation of organic and inorganic polymers. Updates are provided on the preparation of various types of polymers including olefin-sulfur dioxide copolymers, polythioesters, sulfide polymers, polyisocyanates, polyoxyalkylhydroxy compounds, polyvinyl carbazole, polyvinyl acetate, polyallyl esters, and polyvinyl flouride. The procedures were chosen on the basis of safety and to be representative of preparation methods for a general class of polymers. Fundamental and practical information on polymer synthesis is combined with extensive references and reviews of the patent literature. Key Features * Completes the Second Edition of three-volume set * Brings together useful preparative methods for polymers and resins * Organized by functional group * Includes new polymerization methods
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Polymer Synthesis: Theory and Practice

Fundamentals, Methods, Experiments

Author: Dietrich Braun,Harald Cherdron,Helmut Ritter

Publisher: Springer Science & Business Media

ISBN: 3662045737

Category: Technology & Engineering

Page: 333

View: 5770

This Laboratory Manual contains detailed descriptions for the synthesis and characterization of macromolecules. Around 110 elaborated examples, consisting of descriptions of experiments, as well as sufficient theoretical explanations enable the reader to learn about the syntheses, modification, characterization and properties of polymers including recent developments. All experiments can be conducted with adequate laboratory equipment. Suitable for students in organic and polymer chemistry as well as for chemists in industry who want to acquaint themselves with the theoretical and practical aspects of macromolecular chemistry.
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Polymer Synthesis

Author: N.A

Publisher: Springer Science & Business Media

ISBN: 9783540217114

Category: Technology & Engineering

Page: 214

View: 3236

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Handbook of Polymer Synthesis

Part B (In Two Parts)

Author: Hans R. Kricheldorf

Publisher: CRC Press

ISBN: 9780824785154

Category: Technology & Engineering

Page: 1808

View: 2239

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Microwave-assisted Polymer Synthesis

Author: Richard Hoogenboom,Ulrich S. Schubert,Frank Wiesbrock

Publisher: Springer

ISBN: 3319422413

Category: Technology & Engineering

Page: 351

View: 3491

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
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Polymer Synthesis and Characterization

A Laboratory Manual

Author: Stanley R. Sandler,Wolf Karo,JoAnne Bonesteel,Eli M. Pearce

Publisher: Elsevier

ISBN: 9780080539218

Category: Technology & Engineering

Page: 212

View: 2574

This laboratory manual covers important techniques for polymer synthesis and characterization, and provides newcomers with a comprehensive introduction to the basic principles of highlighted techniques. The reader will benefit from the clear writing style and straightforward approach to fairly complex ideas. The book also provides references that the more advanced reader can use to obtain in-depth explanations of techniques. Polymer Synthesis and Characterization will serve as a useful resource for industrial technicians and researchers in polymer chemistry and physics, material science, and analytical chemistry. Combines the extensive industrial and teaching experience of the authors Introduces the user to the concept of "Good Manufacturing Practice" Presents experiments that are representative of a wide variety of polymerization and characterization methods Includes numerous references for more advanced students, technicians, and researcher
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Polymer Syntheses

Organic Chemistry: A Series of Monographs

Author: Stanley R. Sandler,Wolf Karo

Publisher: Elsevier

ISBN: 1483220087

Category: Science

Page: 382

View: 2921

Polymer Syntheses, Volume III provides useful polymer synthesis information. The book discusses the olefin-sulfur dioxide copolymers; the polythioesters; and sulphide polymers. The text also describes polymerizations reactions of mono and diisocyanates; polyoxyalkylation of hydroxyl compounds; and polymerization reactions of N-vinyl carbazole and related monomers. The polymerization of vinyl acetate and other vinyl esters; the polymerization of allyl esters; and the polymerization of vinyl fluoride are also considered. The book further tackles miscellaneous polymer preparations.
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Azo Polymers

Synthesis, Functions and Applications

Author: Xiaogong Wang

Publisher: Springer

ISBN: 366253424X

Category: Technology & Engineering

Page: 230

View: 6469

This book explores functional polymers containing aromatic azo chromophores in side-chain, main-chain and other parts of their structures, known as azo polymers and which share common photoresponsive properties. It focuses on the molecular architecture of azo polymers, the synthetic methods and their most important functions, such as photoinduced birefringence and dichroism, surface-relief-grating (SRG) formation, and light-driven deformation of liquid crystal elastomers. It combines a general survey of the subject and in-depth discussions of each topic, including numerous illustrations, figures, and photographs. Offering a balance between an introduction to the core concepts and a snapshot of hot and emerging topics, it is of interest to graduate students and researchers working in this and related fields. Xiaogong Wang is a Professor at the Department of Chemical Engineering, Tsinghua University, China.
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Topological Polymer Chemistry

Progress of Cyclic Polymers in Syntheses, Properties and Functions

Author: Yasuyuki Tezuka

Publisher: World Scientific

ISBN: 9814401285

Category: Cyclopolymerization

Page: 365

View: 1223

There are examples aplenty in the macroscopic world that demonstrate the form of objects directing their functions and properties. On the other hand, the fabrication of extremely small objects having precisely defined structures has only recently become an attractive challenge, which is now opening the door to nanoscience and nanotechnology.In the field of synthetic polymer chemistry, a number of critical breakthroughs have been achieved during the first decade of this century to produce an important class of polymers having a variety of cyclic and multicyclic topologies. These developments now offer unique opportunities in polymer materials design to create unprecedented properties and functions simply based on the form, i.e. topology, of polymer molecules.In this book on topological polymer chemistry, the important developments in this growing area will be collected for the first time, with particular emphasis on new conceptual insights for polymer chemistry and polymer materials. The book will systematically review topological polymer chemistry from basic aspects to practice, and give a broad overview of cyclic polymers covering new synthesis, structure characterization, basic properties/functions and the eventual applications.
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New Frontiers in Polymer Synthesis

Author: Shiro Kobayashi

Publisher: Springer Science & Business Media

ISBN: 3540698078

Category: Technology & Engineering

Page: 188

View: 1683

It is generally accepted that a new material is often developed by ?nding a new synthesis method of reaction or a new reaction catalyst. Historically, a typical example may be referred to as a Ziegler–Natta catalyst, which has allowed large-scale production of petroleum-based polyole?ns since the middle of the 20th century. New polymer synthesis, therefore, will hopefully lead to creation of new polymer materials in the 21st century. This special issue contributed by three groups focuses on recent advances in polymer synthesis methods, which handle the cutting-edge aspects of the advanced technology. The ?rst article by Yokozawa and coworkers contains an overview of the - action control in various condensation polymerizations (polycondensations). Advanced technologies enabled the control of stereochemistry (regio-, g- metrical-, and enantio-selections), chemoselectivity, chain topology, and st- chiometry of monomers, giving a high molecular weight polymer. It has been recognized for a long time, however, that polycondensation is a dif?cult p- cess in controlling the reaction pathway, because the reaction is of step-growth and the reactivity of monomers, oligomers, and polymers are almost the same during the reaction and hence, the molecular weight of polymers and its d- tribution (M /M ) are impossible to regulate. The authors’ group developed w n a new reaction system (chain-growth condensation polymerization), changing the nature of polycondensation from step-growth to chain-growth; namely the propagating chain-end is active, allowing for control of the product molecular weight as well as the distribution.
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Chemistry of Chlorine-containing Polymers

Syntheses, Degradation, Stabilization

Author: Karl Samoĭlovich Minsker

Publisher: Nova Science Pub Incorporated

ISBN: N.A

Category: Science

Page: 198

View: 6463

Chemistry of Chlorine-Containing Polymers - Syntheses, Degradation, Stabilization
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Thermally stable polymers

syntheses and properties

Author: Patrick E. Cassidy

Publisher: Marcel Dekker Inc

ISBN: N.A

Category: Technology & Engineering

Page: 393

View: 1938

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Polymers as Aids in Organic Chemistry

Author: N.K Mather

Publisher: Elsevier

ISBN: 0323141196

Category: Science

Page: 270

View: 7807

Polymers as Aids in Organic Chemistry covers the broad classifications and application of polymers in organic chemistry. This book is organized into 15 chapters that focus on the transformation of polymers and their role in other reagents that must be easily separated from their final product. After a brief introduction to polymer chemistry, the book presents a tabulation of the various types of polymers that have been used and the methods for their characterization. It then discusses the use of polymers as supports in peptide, oligonucleotide, and oligosaccharide chemistry; in peptide sequencing; in monofunctionalized difunctional compounds preparation, as aids in asymmetric syntheses; and as trapping agents in the determination of reaction intermediates. The subsequent chapters describe the use of polymers as catalysts, with particular emphasis on transition metals immobilized in the polymer matrix and used as catalysts. The concluding chapters examine polymer-immobilized compounds, enzymes, and whole cells that have been used to carry out a large number of reaction, most of which impinge on the area of organic chemistry. Polymer scientists and researchers and organic chemists will find this book invaluable.
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Desk Reference of Functional Polymers

Syntheses and Applications

Author: Reza Arshady

Publisher: Amer Chemical Society

ISBN: N.A

Category: Science

Page: 820

View: 6114

Discusses the synthesis, properties, and current and potential applications of a wide variety of functional polymers in four major areas: radiation effects and applications, opolelectronic properties and applications, chemical and physicochemical applications, and biomedical applications. Reviews the general synthetic methods for preparing functional polymers. Examines functional polymers with properties of interest in such fields as microlithography, photochemistry, nonlinear optics, electrical conductivity, chemical sensors, electron and energy transfer processes, polymeric liquid crystalline networks, chiral liquid crystalline polymers, solar energy utilization, floculation of minerals, catalysis, polymeric dental aids, polymer-drug conjugates, biocompatible polymer surfaces, and drug targeting by functional polymers.
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