Organometallic Chemistry

Author: R. C. Mehrotra

Publisher: New Age International

ISBN: 9788122412581

Category:

Page: 632

View: 547

The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.
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Perspectives in Organometallic Chemistry

Author: Barry R Steele,Constantinos G Screttas

Publisher: Royal Society of Chemistry

ISBN: 1847551645

Category: Science

Page: 332

View: 7853

Organometallic chemistry is an area which touches on, and plays an active role in, all of the traditional divisions of chemistry: inorganic, organic, physical and theoretical. This timely book provides overviews of recent original developments in these areas, including: the synthesis of main group, transition metal and lanthanide organometallics; applications to homogeneous catalysis; structural and theoretical studies; and enantioselective processes. As these topics are currently part of a stream of exciting research with potentially important industrial applications, this title presents informed accounts of state-of-the-art research which will be of great interest to readers. Written by some of the foremost groups in the field and handsomely illustrated throughout, each chapter also provides an extensive bibliography. By introducing areas that are likely to play a prominent role in organometallic chemistry in the near future, Perspectives in Organometallic Chemistry provides an authoritative source of ideas, particularly for all those engaged in research.
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Advances in Organometallic Chemistry

Author: N.A

Publisher: Academic Press

ISBN: 9780080580418

Category: Science

Page: 356

View: 3730

This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancesments in organometallic chemistry. In basic research, Organometallics have contributed inter alia to metal cluster chemistry, surface chemistry, the stablilization of highly reactive species by metal coordination, chiral synthesis, the formulation of multiple bonds between carbon and the other elements and between the elements themselves. Advances in Organometallic Chemistry is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. Metal organic compounds of calcium, strontium, and barium in chemical vapour deposition 17- and 19-electron organometallic complexes Halocarbonyl complexes of molybdenum and tungsten Substituent effects in metallacene chemistry
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Leading Edge Organometallic Chemistry Research

Author: Marin A. Cato

Publisher: Nova Publishers

ISBN: 9781594548536

Category: Science

Page: 225

View: 4988

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. . In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
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Organometallic Chemistry Research Perspectives

Author: Richard P. Irwin

Publisher: Nova Publishers

ISBN: 9781600217807

Category: Science

Page: 309

View: 4149

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers. This book presents leading-edge new research in the field.
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Organometallic Chemistry

Author: M. Green

Publisher: Royal Society of Chemistry

ISBN: 9780854043231

Category: Reference

Page: 564

View: 8039

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
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Organometallic Chemistry

Author: E. W. Abel,F. G. A. Stone

Publisher: Royal Society of Chemistry

ISBN: 0851866816

Category: Science

Page: 496

View: 8018

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
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Basic Organometallic Chemistry

Containing Comprehensive Bibliography

Author: Ionel Haiduc,Jerry J. Zuckerman

Publisher: Walter de Gruyter

ISBN: 3110847884

Category: Science

Page: 504

View: 1939

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The Organometallic Chemistry of the Transition Metals

Author: Robert H. Crabtree

Publisher: John Wiley & Sons

ISBN: 0471718750

Category: Science

Page: 600

View: 4602

Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
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Organometallic Chemistry

Author: Edward W. Abel

Publisher: Royal Society of Chemistry

ISBN: 0851866905

Category: Reference

Page: 547

View: 7653

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
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NMR in Organometallic Chemistry

Author: Paul S. Pregosin

Publisher: John Wiley & Sons

ISBN: 3527330135

Category: Science

Page: 392

View: 5911

The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis.
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Grundlagen der metallorganischen Komplexkatalyse

Author: Dirk Steinborn

Publisher: Springer-Verlag

ISBN: 3834893757

Category: Science

Page: 434

View: 8497

Die Katalyse ist als grundlegendes Prinzip zur Überwindung der kinetischen Hemmung chemischer Reaktionen von fundamentaler Bedeutung in der Chemie und die metallorganische Komplexkatalyse ist ein Eckpfeiler der modernen Chemie. Das trifft gleichermaßen für die Grundlagen- und angewandte Forschung wie für industrielle Anwendungen zu. Ausgehend von den Prinzipien der Katalyse und den katalytisch relevanten metallorganischen Elementarschritten werden wichtige metallkomplexkatalysierte Reaktionen behandelt, wobei das mechanistische Verständnis im Vordergrund steht. Besonderer Wert wird dabei auf aktuelle Entwicklungen gelegt. Asymmetrische Synthesen finden ausführlich Berücksichtigung und an ausgewählten Beispielen wird die katalytische Wirkung von Metalloenzymen aufgezeigt. Am Beispiel der Stickstofffixierung werden die drei großen Gebiete der Katalyse – die homogene, die heterogene und die enzymatische Katalyse – vergleichend betrachtet. In der 2. Auflage ist ein neues Kapitel zur Stickstofffixierung hinzugekommen. In diesem werden vergleichend die heterogen katalysierte Reaktion, die enzymatisch katalysierte Reaktion (Nitrogenasen) sowie die homogen katalysierte Reaktion gegenübergestellt.
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Organometallic Chemistry and Catalysis

Author: Didier Astruc

Publisher: Springer Science & Business Media

ISBN: 3540461280

Category: Science

Page: 608

View: 457

This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
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New frontiers in organometallic and inorganic chemistry

proceedings of the second China-Japan-U.S.A. Trilateral Seminar on Organometallic Chemistry and Inorganic Chemistry held in Shanghai, The People's Republic of China, June, 1982

Author: Yaozeng Huang,Akio Yamamoto,B. K. Teo

Publisher: N.A

ISBN: N.A

Category: Science

Page: 530

View: 1661

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Organometallic Chemistry

Author: Ian J. S. Fairlamb,Jason M. Lynam

Publisher: Royal Society of Chemistry

ISBN: 1849733767

Category: Reference

Page: 127

View: 9369

A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields."
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Focus on Organometallic Chemistry Research

Author: Marin A. Cato

Publisher: Nova Publishers

ISBN: 9781594544958

Category: Science

Page: 201

View: 9519

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
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Organometallic Chemistry

A review of the literature published during 1971

Author: R. K. Harris

Publisher: Royal Society of Chemistry

ISBN: 0851865011

Category: Reference

Page: 521

View: 363

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.
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Organometallic Chemistry

Author: Royal Society of Chemistry (Great Britain)

Publisher: Royal Society of Chemistry

ISBN: 0854043489

Category: Science

Page: 332

View: 6951

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry.
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